[Cu(HDPC)2]·(HOx)2·6H2O的合成及晶体结构 |
Synthesis and Crystal Structure of [CU(HDPC)2]·(HOx)2·6H2O |
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关键词: 铜 配合物 吡啶-2 6-二甲酸根 晶体结构 |
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Abstract: The new complex formulated [CU(HDPC)2]·(HOx)2·6H2O(HDPC- is pyridine-2,6-dicarb-oxylate,Hoxis 8-Hydroxyquindine) has been synthesized and the crystal structure was determined by X-ray diffraction .The crystal structure of the complex belongs to monoclinic system with space group C2/c. a=18.423(3)Å, b=10.384(2)Å,c=19.139(2)Å, α=γ=90°, β=111.050(10)°, V=3417.0(9)Å3, Z=4, Dc=1.544Mg·m-3, μ=0.722mm-1. In the crystal Cu(Ⅱ) ion is six coordinated to form a distorted octahedron. |
Keywords: copper complex pyridine-2,6-dicarboxylate crystal structure |
投稿时间:2001-02-26 修订日期:2001-04-16 |
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蒋毅民,银秀菊.[Cu(HDPC)2]·(HOx)2·6H2O的合成及晶体结构[J].无机化学学报,2001,17(4):589-592. |
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