[Cu(HDPC)2]·(HOx)2·6H2O的合成及晶体结构
Synthesis and Crystal Structure of [CU(HDPC)2]·(HOx)2·6H2O
作者单位
蒋毅民 广西师范大学化学系, 桂林541004 
银秀菊 广西师范大学化学系, 桂林541004 
摘要: 
关键词:   配合物  吡啶-2  6-二甲酸根  晶体结构
基金项目: 
Abstract: The new complex formulated [CU(HDPC)2]·(HOx)2·6H2O(HDPC- is pyridine-2,6-dicarb-oxylate,Hoxis 8-Hydroxyquindine) has been synthesized and the crystal structure was determined by X-ray diffraction .The crystal structure of the complex belongs to monoclinic system with space group C2/c. a=18.423(3)Å, b=10.384(2)Å,c=19.139(2)Å, α=γ=90°, β=111.050(10)°, V=3417.0(9)Å3, Z=4, Dc=1.544Mg·m-3, μ=0.722mm-1. In the crystal Cu(Ⅱ) ion is six coordinated to form a distorted octahedron.
Keywords: copper  complex  pyridine-2,6-dicarboxylate  crystal structure
投稿时间:2001-02-26 修订日期:2001-04-16
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蒋毅民,银秀菊.[Cu(HDPC)2]·(HOx)2·6H2O的合成及晶体结构[J].无机化学学报,2001,17(4):589-592.
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