| Synthesis of [MoOS3Cu3I(3, 5-diMePy)4]·CH3CN and (Et4>N)4[Mo4Cu8O4S12{(Ph2PS)2N}4] from Solid State Product [Et< |
| Synthesis of [MoOS3Cu3I(3, 5-diMePy)4]·CH3CN and (Et4>N)4[Mo4Cu8O4S12{(Ph2PS)2N}4] from Solid State Product [Et< |
| 作者 | 单位 | | NIUYun-Yin | State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093 | | ZHANGQian-Feng | State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093 | | XINXin-Quan | State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093 | | FUNHoong-Kun | X-Ray Crystallography Unit, School of Physics, Universiti Sains Malaysia 11800 USM, Penang, Malaysia |
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| 摘要: Treatment of iodide bridged dimer [NEt4]4[Mo2O2S6Cu6I4Br2] 1 with 3,5-bimethylpyridine or with Kin CH3CN afforded the tetranuclear cluster [MoOS3Cu3I(3,5-diMePy)4]·CH3CN 2 and dodecanuclear cluster (Et4N)4[Mo4Cu8O4S12{(Ph2PS)2N}4] 3. Monomeric 2 possess a nest shaped skeleton. The structure of oligomeric 3 can be regarded as a tetramer of nest shaped MoCu3OS3 groups co polymerized by sharing the limbic Cu atoms. |
| 关键词: solid state reaction nest-shape structure oligomeric cluster |
| 基金项目: Supported by the National Science Foundation of China(No.29631040). |
| Abstract: Treatment of iodide bridged dimer [NEt4]4[Mo2O2S6Cu6I4Br2] 1 with 3,5-bimethylpyridine or with Kin CH3CN afforded the tetranuclear cluster [MoOS3Cu3I(3,5-diMePy)4]·CH3CN 2 and dodecanuclear cluster (Et4N)4[Mo4Cu8O4S12{(Ph2PS)2N}4] 3. Monomeric 2 possess a nest shaped skeleton. The structure of oligomeric 3 can be regarded as a tetramer of nest shaped MoCu3OS3 groups co polymerized by sharing the limbic Cu atoms. |
| Keywords: solid state reaction nest-shape structure oligomeric cluster |
| 投稿时间：2001-04-15 修订日期：2001-05-22 |
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| NIUYun-Yin,ZHANGQian-Feng,XINXin-Quan,FUNHoong-Kun.Synthesis of [MoOS3Cu3I(3, 5-diMePy)4]·CH3CN and (Et4>N)4[Mo4Cu8O4S12{(Ph2PS)2N}4] from Solid State Product [Et<[J].无机化学学报,2001,17(4):489-490. |
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