| 钼磷酸和2-吡啶-偶氮-2萘酚电荷转移配合物的合成、表征及性质研究 |
| Synthesis, Characterization and Properties of Charge-Transfer Complex Based on Molybdophosphoric Acid and α-Phridylazo-β- Naphthol |
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| 摘要: |
| 关键词: 钼磷酸 电荷转移配合物 光致变色 |
| 基金项目: 湖北省重点科技攻关项目(No.992PO321) |
| Abstract: A new photosensitive charge transfer complex has been synthesized based on phosphomolybdic acid and α-phridylazo-β-naphthol and characterized by elemental analysis, IR spectrum, UV spectrum, The resalts of IR spectra showed that the coordinating atom of α-phridylazo- β-naphthol was oxygen of C-O bond.The organic ligands do not coordinate with heteropolyanions, but with Protons in heteropoly acid by coordination bond.Photochromism studies show that the electron transfer takes place from the organic molecules to the heteropolyanions. |
| Keywords: phosphomolybdic acid charge transfer complex photorhromism |
| 投稿时间：2000-09-22 修订日期：2000-12-19 |
| 摘要点击次数: 1200 |
| 全文下载次数: 1625 |
| 靳素荣,姚礼峰,陈永熙.钼磷酸和2-吡啶-偶氮-2萘酚电荷转移配合物的合成、表征及性质研究[J].无机化学学报,2001,17(2):289-291. |
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