硫酸铝钾热分解反应动力学模型 |
Kinetics Model of Thermal Decomposition Reaction of Aluminum Potassium Sulphate |
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摘要: |
关键词: 硫酸铝钾 热分解 动力学 |
基金项目: 河北师范大学科学研究基金 |
Abstract: The thermal decomposition process of KAI(SO4)2·12H2O and its kinetics has been studied by TG-DTG.By Dollimore method, D3 is defined as the second step of thermal decomposition kinetic model and its kinetic equation is dα/dT = (1/β) CTm(3/2(1 - α)2/3[1-(1-a)1/3]-1).At the same time, it has been found that the apparent activation energy Eincreases with the increases of fraction of conversion a and the absolute temperature T, and then it shows that a linear relationship with the temperature Thas been obtained. |
Keywords: aluminum potassium sulphate thermal decomposition kinetic model |
投稿时间:2000-09-01 修订日期:2000-10-23 |
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张建军,魏海玉,任志强.硫酸铝钾热分解反应动力学模型[J].无机化学学报,2001,17(2):279-284. |
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