| 具二维网格的氟喹诺酮类铜配合物的合成和晶体结构 |
| Synthesis and Crystal Structure of Fluoroquinolone Complex of Copper with Two Dimension Network |
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| 摘要: |
| 关键词: 合成 晶体结构 铜 氟喹诺酮类 |
| 基金项目: 浙江省分析测试基金(No.99057) |
| Abstract: The 2-D coordination polymer network containing fluoroquinolone ligand, {[Cu(L)(bipy)](C2H5OH)(5H2O)}n, was synthesized and its crystal structure was solved. The formula of the complex is C30H40N5FO11Cu and the crystallography data are as follows, monoclinic, space group P21/c(No.14),a=11.937(3)Å,b=10.555(3)Å,c=25.293(9)Å,β =98.82(3)°, V= 3148(1)Å3 and Z=4. Two carboxylate groups monodentately bind to copper atoms and the 4-oxo group is linked to copper atom. The Cu ion displays a distorted square-pyramidal coordination and its coordination number is five. |
| Keywords: synthesis crystal structure copper fluoroquinolone |
| 投稿时间：2000-07-10 修订日期：2000-08-23 |
| 摘要点击次数: 1507 |
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| 王国平,蔡国强,朱龙观.具二维网格的氟喹诺酮类铜配合物的合成和晶体结构[J].无机化学学报,2000,16(6):987-990. |
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