三甲基镓与氨基亚甲基酚配合物的合成与表征
Synthesis and Characterization of Complexes Formed by Trimethyl Gallium and Aminomethyl Phenols
作者单位
沈曦 南京大学化学化工学院, 南京 210093 
陈化冰 南京大学化学化工学院, 南京 210093 
张进琪 南京大学化学化工学院, 南京 210093 
毕武 南京大学化学化工学院, 南京 210093 
邹惠仙 南京大学环境学院, 污染控制与资源化研究国家重点实验室, 南京 210093 
摘要: 
关键词: 三甲基镓  氨基亚甲基酚  合成  表征
基金项目: 国家863高技术研究项目(No.715-001-0060)
Abstract: Eight new bi-nuclearcomplexes: Bis(dimethylgallium)-μ-(4,4′-disubstituted-2,2′-[piperazine-1,4-diylbis(methylene)]-bisphenol (complexes 1~7)(substituted group =H,CH3,OCH3,Cl,Br,C(CH3)3,C6H5) and Bis(dimethylgallium)-μ-(2,2′-[piperazine-1,4-diylbis(methylene)]-bisnaphthol (complexes 8) were preparedby the reaction of trimethyl gallium with aminomethyl Phenols. The molecular structure were confirmed by elemental analysis,1HNMR, IR and MS. It is important to study the structure of the complexes for seeking new source and developing MOCVD techniques.
Keywords: trimethyl gallium  aminomethyl phenols  synthesis  characterization
投稿时间:2000-04-25 修订日期:2000-06-15
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沈曦,陈化冰,张进琪,毕武,邹惠仙.三甲基镓与氨基亚甲基酚配合物的合成与表征[J].无机化学学报,2000,16(6):973-977.
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