| [Lu(POA)3(phen)]n的合成及晶体结构 |
| Synthesis and Crystal Structure of [Lu(POA)3phen]n |
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| 摘要: |
| 关键词: 镥 配合物 苯氧乙酸 晶体结构 |
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| Abstract: The new ternary complex of [Lu(POA)3phen]n (POA is phenoxy acetic acid, phen is 1,10-phenanthroine) was synthesized and crystal structure was determined by X-ray diffraction.The crystal structure belongs to monoclinic system with space group P21/n.a=20.394(3)Å,b=8.513(1)Å, c=20.708(3)Å,β =107.70(1)°,V=3425.1(8)Å3,Z=4,Dc=1.568Mg·m-3,μ(MoKα)=2.939mm-1. Each Lu3+ ion is nine coodinated. Coordination polyhedron is a distorted trigonal prism. The carboxylate groups in the complex are bonded to the lutetium ion in the bridged bidentate and the bridged tridentate. Lutetium ions were linked by the bridged carboxylate groups, resulting in an infinite chain. |
| Keywords: lutetium complex phenoxy acetic acid crystal structure |
| 投稿时间：2000-06-14 修订日期：2000-09-05 |
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| 邓洪,陈超球,梁利芳,李丽琳,郁开北.[Lu(POA)3(phen)]n的合成及晶体结构[J].无机化学学报,2000,16(6):969-972. |
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