| 咪唑配合物[Co(C3H4N2)6](PhCHCHCOO)2的合成及晶体结构 |
| Synthesis and Crystal Structure of Hexakis(imidazole) Cobalt(Ⅱ)Dicinnamate [Co(C3H4N2)6](PhCHCHCOO)2 |
| 作者 | 单位 | | 赵朴素 | 南京理工大学, 材料化学研究室, 南京 210094 | | 建方方 | 南京理工大学, 材料化学研究室, 南京 210094 | | 陆路德 | 南京理工大学, 材料化学研究室, 南京 210094 | | 杨绪杰 | 南京理工大学, 材料化学研究室, 南京 210094 | | 汪信 | 南京理工大学, 材料化学研究室, 南京 210094 | | RAJ S. Shanmuga-Sundara | X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia 11800 USM, Penang, Malaysia | | FUN Hoong-Kun | X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia 11800 USM, Penang, Malaysia |
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| 摘要: |
| 关键词: 咪唑配合物 肉桂酸钴 CoN6生色基 晶体结构 氢键 三维网状结构 |
| 基金项目: 江苏省自然科学基金(No.BK99072) |
| Abstract: The complex [Co(Im)6](Cin)2 (Im=imidazole,Cin=cinnamate) was prepared by reaction of Co(PhCHCHCOO)2 with imidazole in ethanol. It has been determined by single crystal X-ray analyses. The crystals are triclinic, space group P1, with a=9.7601(3),b=10.5935(3),c=11.3269(2)Å,α =69.948(1),β =71.027(1),γ =62.803(1)°, and Z=1. The crystal structure of the title complex consists of monomeric [Co(Im)6]2+ cations and cinnamate anions in which the cobalt(Ⅱ) ion assumes a centrosymmetric octahedral geometry with the CoN6 chromophore. In the solid state, the complex forms a three dimensional network through N－H… O hydrogen bonds, the intermolecular hydrogen bonds connect the [Co(Im)6]2+ cations and cinnamate anions.The cinnamate anions are nearly planar. |
| Keywords: imidazole complexes cinnamate cobalt(Ⅱ) CoN6 chromophore crystal structure hydrogen bond three-dimensional network |
| 投稿时间：2000-04-20 修订日期：2000-06-22 |
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| 赵朴素,建方方,陆路德,杨绪杰,汪信,RAJ S. Shanmuga-Sundara,FUN Hoong-Kun.咪唑配合物[Co(C3H4N2)6](PhCHCHCOO)2的合成及晶体结构[J].无机化学学报,2000,16(6):964-968. |
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