| 二甲基[2-(2-苯并噁唑)苯酚氧基]镓、铟化合物的合成及表征 |
| Synthesis and Characterization of Dimethyl[2(2-benzoxazolyl)phenolato] Gallium or Indium Complexes |
|
| 摘要: 通过2-(2-苯并噁唑)-4-甲氧基苯酚、2-(2-苯并噁唑)苯酚与三甲基镓、三甲基铟反应,合成了四个新的金属有机化合物,并用元素分析、质子核磁共振谱、质谱及红外光谱等手段对化合物进行了结构表征。对其中一个化合物二甲基[2-(2-苯并噁唑)-4-甲氧基苯酚氧基]镓进行了X-衍射单晶分子结构测定,该化合物属于三斜晶系,空间群为P1。晶体学常数:a=7.4992(2)Å,b=10.199(2)Å,c=10.905(2)Å,α=110.18(3)°,β=102.23(3)°,γ=9 |
| 关键词: 2-(2-苯并噁唑)苯酚 三甲基镓 三甲基铟 配合物 晶体结构 |
| 基金项目: 江苏省自然科学基金(No.BK99028);家863计划资助(No.863-715-001-0060) |
| Abstract: Four new compounds were prepared by the reaction of 2-(2-hydroxylbenzyl)benzoxazole、 2-(2-hydroxyl-4-methoxybenzyl)benzoxazole with trimethylgallium or trimethylindium. The compounds obtained have been characterized by 1H NMR、 IR、 MS spectroscopy and elemental analysis. Molecular structure of the compound dimethyl[2-(2-benzoxazolyl)-4-methoxyphenolato]gallium has been determined by single crystal X-ray analysis. The crystal structure belongs to triclinic system with space group P1,a=7.4992(2)Å,b=10.199(2)Å,c=10.905(2)Å,α =110.18(3)° ,β =102.23(3)° ,γ =94.58(3)° ,V=753.7(3)Å3,Z=4,Dc=1.489g·cm-3,F(000)=348. The compound is monomeric and the gallium atom in the complex is four coordinate in tetrahedral geometry. |
| Keywords: 2-(2-hydroxylbenzyl)benzoxazole trimethylgallium trimethylindium crystal stuctu |
| 投稿时间：2000-06-27 修订日期：2000-09-08 |
| 摘要点击次数: 1698 |
| 全文下载次数: 2197 |
| 徐代旺,潘毅,孙祥祯,吴锵金.二甲基[2-(2-苯并噁唑)苯酚氧基]镓、铟化合物的合成及表征[J].无机化学学报,2000,16(6):945-950. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
