La2NiO4+δ的非化学计量与氧渗透性能 |
Nonstoichiometry and Oxygen Permeability in La2NiO4+δ |
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摘要: 采用质量损失法、碘量滴定法和正电子湮没寿命谱研究了La2NiO4+δ透氧膜的非化学计量,并表征了该材料的氧渗透性能,探讨了La2NiO4+δ的非化学计量缺陷与氧渗透性能之间的关系。研究结果表明,La2NiO4+δ的氧渗透通量随δ的增大而增大。 |
关键词: La2NiO4+δ 致密透氧膜 非化学计量 氧渗透性能 |
基金项目: 中科院上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室资助 |
Abstract: Oxygen stoichiometry of La2NiO4+δ was determined by thermogravimetric analysis, iodometry and positron annihilation lifetime spectra analysis, and oxygen permeating flux was measured. The relationship between nonstoichiometry and oxygen permeability in La2NiO4+δ was discussed. The results show that oxygen permeating flux increases with increasing the extra exygen content (δ ). |
Keywords: La2NiO4+δ dense oxygen permeating membrane nonstoichiometry oxygen permeabil |
投稿时间:2000-04-11 修订日期:2000-06-22 |
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张华,金江,余桂郁,杨南如,周先意.La2NiO4+δ的非化学计量与氧渗透性能[J].无机化学学报,2000,16(6):911-915. |
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