盐卤硼酸盐化学XXX-MgO·2B2O3-18%MgCl2-H2O过饱和溶液结晶动力学 |
Chemistry of Borate in Salt Lake Brine X X IX ──Crystallization Kinetics of Mg-borates from MgO·2B2O3-18%MgCI2-H2O Supersaturated Solution |
|
摘要: 对MgO·2B2O3-18%MgCl2-H2O过饱和溶液在不同温度条件下的结晶动力学过程进行测定,给出结晶动力学方程。析出固相采用X-射线粉末衍射、红外光谱和热分析进行物相鉴定。提出使用结晶法合成章氏硼镁石的新方法。 |
关键词: 章氏硼镁石 结晶动力学 过饱和溶液 |
基金项目: 国家自然科学基金资助项目(No.29971032) |
Abstract: The crystallization processes of Mg-borates from MgO·2B2O3-18 % MgCl2-H2O supersaturated solution at different temperature have been studied by kinetic method and the crystallization kinetic equations were fitted with the experimental data by computer.The solid phases were identified by IR-spectra, X-ray powder diffraction and TC-DTG-DSC thermal analysis.The new synthetic method of hungchaoite has been firstly proposed. |
Keywords: hungchaoite crystallization kinetics supersaturated solution |
投稿时间:2000-01-11 修订日期:2000-03-30 |
摘要点击次数: 1933 |
全文下载次数: 1643 |
朱黎霞,高世扬,夏树屏,张逢星.盐卤硼酸盐化学XXX-MgO·2B2O3-18%MgCl2-H2O过饱和溶液结晶动力学[J].无机化学学报,2000,16(5):722-728. |
查看全文 查看/发表评论 下载PDF阅读器 |
Support information: |
|
|
|