| Mn(Ⅲ)Schiff碱配合物的合成、结构及性能 |
| Synthesis,Structures and Properties of Mn(Ⅲ) Schiff Base Complexes |
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| 摘要: 合成Schiff碱配体C20H14N2(OH)2(N,N'-双水杨醛缩邻苯二胺)及相应的两个新Mn(Ⅲ)C20H14N2(OH)2配合物[Mn(C20H14N2O2)(H2O)(CH3OH)]ClO |
| 关键词: Schiff碱 锰配合物 晶体结构 |
| 基金项目: 陕西省教委专项基金资助项目(HF982224) |
| Abstract: Mn(Ⅲ) Schiff base complexes of [Mn(C20H14N2O2)(H2O)(CH3OH)]ClO4(1)and [Mn(C20H14N2O2)(C7H5O2)]·CH3CN(2) have been synthesized and structurally characterized by X-ray method. The crystal of complex 1 belongs to monoclinic, space group P21/n, with a=1.1748(7)nm, b=1.3985(7)nm, c=1.3538(4)nm,β=92.63°,V=2.222(2)nm3, Z=4; The crystal of complex 2 belongs to monoclinic, space group P21/n,with a=1.0252(2)nm,b=2.0146(3)nm, c=1.2494(4) nm, β=111.12(2)°,V=2.407(2) nm3, Z=4. The UV-Vis spectra have also been determined. |
| Keywords: Schiff base manganese(Ⅲ) complex crystal structure |
| 投稿时间：1999-06-08 修订日期：1999-07-23 |
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| 李君,杨术明,张逢星,唐宗薰,史启祯,吴锵金,黄子祥.Mn(Ⅲ)Schiff碱配合物的合成、结构及性能[J].无机化学学报,2000,16(1):84-88. |
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