| 一种合成平面双核金属酞菁的新方法 |
| A NEW SYNTHESIS METHOD OF PLANAR BINUCLEAR BISPHTHALOCYANINATO-METAL |
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| 摘要: |
| 关键词: 平面双核金属酞菁 酸酐路线 合成 |
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| Abstract: A new planar binuclear bisphthalocyaninato-metal-planar hexa-tert-butylbisphthalocyaninato dicobalt (Ⅱ) was synthesized by the reaction of 4-tert-butylphthalic anhydride with pyromellitic dianhydride, urea and CoCl2·6H2O. This is a new synthesis method (phthalic route). The total yield reaches up to 15%. The synthetic reaction conditions are as follows: appropriate molar ratio of the reactant, reaction in solid phase and without ammonium molybdate as catalyst. |
| Keywords: planar binuclear bisphthalocyaninato-metal phthalic anhydride route synthesis |
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| 唐代华,王小兵,甄珍,王凤奇,刘新厚.一种合成平面双核金属酞菁的新方法[J].无机化学学报,1999,15(6):821-825. |
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