| FeCo2(CO)9(μ3-S)簇合物羰基取代衍生物的合成与表征 | |||||||||||
| SYNTHESES AND CHARACTERIZATION OF CARBONYL SUBSTITUTED DERIVATIVES OF FeCo2(CO)9(μ3-S) CLUSTER COMPOUND | |||||||||||
|
|||||||||||
| 摘要: | |||||||||||
| 关键词: 羰基取代 混金属簇 合成 | |||||||||||
| 基金项目: | |||||||||||
| Abstract: Mono-、 di- and tri-substituted derivatives of FeCo2(CO)9(μ3-S) with P(OR)3 were synthesized. They have the following formular, FeCo2(CO)9-n(μ3-S)［P(OR)3］n ［n=1, R=CH2CH2CH3(a); n=1,2,3, R=CH2CH2CH2CH3(b); n=1,2,R=CH(CH3)(CH2)2CH3(c)］. The six new compounds were characterized by elemental analysis, IR, 1H NMR and MS spectra and their molecular structures were deduced. | |||||||||||
| Keywords: carbonyl replacement mixed metal cluster syntheses | |||||||||||
| 摘要点击次数: 1315 | |||||||||||
| 全文下载次数: 1355 | |||||||||||
| 王晓玲,乌仁,索全伶,王一兵.FeCo2(CO)9(μ3-S)簇合物羰基取代衍生物的合成与表征[J].无机化学学报,1999,15(6):809-812. | |||||||||||
| 查看全文 查看/发表评论 下载PDF阅读器 | |||||||||||
| Support information: | |||||||||||
|
| |||||||||||
|
| |||||||||||
|
| |||||||||||