| N-(2-吡啶基)-伯胺·二甲基合镓(Ⅲ)的制备及表征 |
| SYNTHESIS AND CHARACTERIZATION OF N-(2-PYRIDYLMETHYL)-N-ARYLAMIDO(DEMETHYL)GALLIUM COMPLEXES |
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| 摘要: 通过2-甲酰基吡啶与胺缩合制得Schiff碱，经NaBH4还原得到四个N-(2-吡啶甲基)芳胺(芳基=苯基，邻甲氧基苯基，对甲苯基及2-吡啶基)，得到的芳胺及N-(2-吡啶乙基)甲胺与三甲基镓反应生成相应的N-(2-吡啶基)伯胺·二甲基合镓(Ⅲ)配合物。用元素分析、红外光谱、质子核磁共振、质谱等手段对配合物进行了结构鉴定和表征。 |
| 关键词: 三甲基镓 配合物 合成 氮化镓 单一源 |
| 基金项目: |
| Abstract: Five intramolecular pyridyl coordinated amidogallium complexes, (2-pyridyl)CH2NRGa(CH3)2(R=C6H4-, p-CH3C6H4-, o-CH3OC6H4-, 2-pyridyl-) and (2-pyridyl)CH2CH2N(CH3)Ga(CH3)2, have been synthesized and characterized by IR, 1H NMR, MS and elemental analysis. Molecular ion peaks of the complexes are visible in their MS spectra. |
| Keywords: timethylgallium complex syntheses gallium nitride single source precursors |
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| 郑昊,沈应中,顾宏伟,潘毅,顾伟瑾.N-(2-吡啶基)-伯胺·二甲基合镓(Ⅲ)的制备及表征[J].无机化学学报,1999,15(3):336-340. |
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