| Abstract: The protonation constants of the macrocycle H2L1 (c-meso-2,4,4,11,13,13-hexamethyl-1,5,10,14-tetraazacyclooctadecane-N,N＂-diacetic acids)were determined potentiometricly and by computer fitting in 0.5 mol·L-1 KNO3 solution at 25±0.1℃, 30±0.1℃ and 40±0.1℃. The stability constants of the 1∶1 complexes of H2L1 with La3+, Nd3+, Sm3+, Eu3+, Gd3+, Dy3+, Yb3+ were determined by the same method at 40±0.1℃. The ΔH、 ΔS and ΔG of the coodination reaction of H2L1 with H+ in the aqueous solution were found. |
