| 三齿NS2型配体Cu(Ⅱ)配合物的合成、光谱性质及电化学性质 |
| SYNTHESIS, SPECTRAL AND ELECTROCHEMICAL PROTERTIES OF Cu(Ⅱ) COMPLEXES WITH TRIDENTATE NS2 LIGANDS |
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| 摘要: |
| 关键词: Cu(Ⅱ)配合物 三齿SN2型配体 模型化合物 |
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| Abstract: A variety of complexes Cu(NS2)(Im)(NO3)2 and Cu(NS2)(Py)(NO3)2 where NS2=HN(CH2CH2SR)2(R=CH3CH2CH2, (CH3)2CH,CH3CH2CH2CH2 and (CH3)2CHCH2), have been synthesized and characterized by elementary analyses, molar conductivity, IR, UV/Vis and ESR spectra as well as by electrochemical methods. The new complexes exhibit exceptionally high redox potentials(500～580 mV) and complexes for HN(CH2CH2SCH(CH3)2)2 exihibit rather hyperfine splitting constants(a‖<70G) in the powder ESR spectra, which are close to those for the blue copper proteins. |
| Keywords: copper(Ⅱ) complexes tridentate NS2 ligands model compounds for the blue copper proteins |
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| 乐学义,石巨恩.三齿NS2型配体Cu(Ⅱ)配合物的合成、光谱性质及电化学性质[J].无机化学学报,1999,15(1):128-131. |
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