| 含嘧啶环的双冠醚——V.双冠醚为载体的碱金属离子选择性电极的研究 |
| BIS-CROWN ETHER CONTAINING PYRIMIDINE RING——Ⅴ. SODIUM, POTASSIUM AND CAESIUM ION SELECTIVE PVC MEMBRANE ELECTRODES BASED ON BIS-CROWN ETHERS AS CARRIER |
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| 摘要: 本文报道由5-硝基-6-三氟甲基嘧啶环桥联苯并-12-冠-4、苯并-15-冠-5和苯并-18-冠-6的三种新的双冠醚的合成。用它们作为载体分别制成钠、钾和铯离子选择性电极，测定了电极的响应功能、选择性系数和适用的pH范围。结果表明三种电极都有较好的性能。 |
| 关键词: 双冠醚 嘧啶环 膜电极 碱金属离子 选择性系数 |
| 基金项目: |
| Abstract: Sodium, potassium and caesium ion selective PVC membrane electrodes based on nine new bis-crown ethers containing benzo-12-crown-4(1), benzo-15-crown-5(2) and benzo-18-crown-6(3) moieties bridged by pyrimidine ring were prepared and their electrode behaviours were evaluated. The electrodes (1), (2) and (3) exhibited good Nernstian responses and respectively better selectivity with respect to all other alkali and alkaline earth metal cations. |
| Keywords: bis-crown pyrimidine ring sodium ion potassium ion caesium ion membrane electrode selectivity coefficient |
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| 陆国元,王志林,宋伟,胡宏纹.含嘧啶环的双冠醚——V.双冠醚为载体的碱金属离子选择性电极的研究[J].无机化学学报,1998,14(3):257-260. |
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