| 新型手性骨架异核原子簇化合物的合成及表征 |
| SYNTHESIS AND CHARACTERIZATION OF NOVEL TYPE CHIRAL SKELETON HETERONUCLEAR CLUSTER COMPOUNDS |
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| 摘要: 首次合成了未见文献报道的两种新的手性簇合物，(μ3-S)FeCoW(CO)8C5H4C(O)R (R=C6H5、C6H5C(O)OCH3)，对其合成、谱学性质及晶体结构进行了研究。 |
| 关键词: 异核原子簇合物 手性骨架 晶体结构 |
| 基金项目: |
| Abstract: The reaction of the monoanion ［η5-C5H4R(CO)3W］-with SFeCo2(CO)9 yields the new clusters SFeCoW(CO)8RC5H4［R=C6H5C(O)、 CH3O(O)CC6H4C(O)］. The clusters were characterized by C/H analysis, IR, 1H NMR and the cluster SFeCoW(CO)8C5H4C(O)C6H4C(O)OCH3 was determined by single crystal X-ray diffraction. |
| Keywords: heteronuclear cluster compound chiral skeleton crystal structure |
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| 丁二润,李庆山,刘省明,殷元骐,孙杰.新型手性骨架异核原子簇化合物的合成及表征[J].无机化学学报,1998,14(2):219-221. |
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