| 1，4-双(1′-苯基-3′-甲基-5′-氧代吡唑-4′-基)丁二酮-(1，4)合双铜(Ⅱ)配合物的合成、表征、非等温热分解反应动力学及电化学性质 |
| SYNTHESIS, CHARACTERIZATION, NON-ISOTHERMAL KINETIC OF THE THERMAL DECOMPOSITION AND ELECTROCHEMICAL PROPERTIES OF 1,4-BIS-(1′-PHENYL-3′-METHYL-5′-PYRAZOLONE-4′)-1,4-BUTANEDIONE COPPER(Ⅱ) BINUCLEAR COORDINATION COMPOUND |
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| 摘要: |
| 关键词: β-二酮 双核配合物 非等温热分解 电化学性质 |
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| Abstract: The paper reported the synthetic procedure and character of Copper(Ⅱ) binuclear coordination compound of 1,4-bis-(1′-phenyl-3′-methyl-5′-pyrazolone-4′)-1,4-butanedione. The non-isothermal kinetic of the thermal decomposition of the complex has been studied from the TG-DTG curves by means of the Achar et al and Coats-Redfern methods. The electrochemical characterization of the complex were studied by means of powder microelectrodes technique. |
| Keywords: Cu(Ⅱ) binuclear coordination compound non-isothermal thermal decomposition electrochemical property β-dione |
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| 单纯,贾殿赠,夏熙.1，4-双(1′-苯基-3′-甲基-5′-氧代吡唑-4′-基)丁二酮-(1，4)合双铜(Ⅱ)配合物的合成、表征、非等温热分解反应动力学及电化学性质[J].无机化学学报,1997,13(4):433-436. |
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