希土(Ⅲ)噻吩甲酰三氟丙酮和BipyO2/PhenNO三元配合物的合成和表征 |
SYNTHESIS AND CHARACTERIZATION OF RARE EARTH(Ⅲ) TERNARY COMPLEXES WITH THENOYLTRIFLUOROACETONATE AND BipyO2 or PhenNO |
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摘要: |
关键词: 希土 三元配合物 噻吩甲酰三氟丙酮 荧光光谱 |
基金项目: |
Abstract: The new ternary complexes of RE(TTA)3(BipyO2)·H2O and RE(TTA)3 (PhenNO)(where RE=Sm, Eu, Gd; TTA=thenoyltrifluoroacetonate; BipyO2=2,2′-bipyridine-N,N′-dioxide; PhenNO=1,10-phenanthroline-N-oxide)have been synthesized. The composition and properties of complexes were studied by elemental analysis, UV spectrum, IR spectrum, DTA-TG and fluorescence spectrum. The effect of solvent on fluorescent intensity is discussed. |
Keywords: rare earth ternary complex thenoyltrifluoroacetone fluorescent spectra |
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成义祥,徐端钧,徐元植.希土(Ⅲ)噻吩甲酰三氟丙酮和BipyO2/PhenNO三元配合物的合成和表征[J].无机化学学报,1997,13(2):234-236. |
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