| 铜(Ⅱ)与N-苯甲酰缬氨酸和二胺类混配配合物的合成与表征 |
| SYNTHESIS AND CHARACTERIZATION OF MIXED LIGAND COMPLEXES OF COPPER (Ⅱ) WITH N-BENZOYLVALINE AND DIAMINE |
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| 摘要: 首次合成了四种铜(Ⅱ)与N-苯甲酰缬氨酸(Bval-O)与二胺(DA)类的混配配合物［Cu(Bval-O)2(DA)］，DA=乙二胺(en)，2，2′-联吡啶(bpy),1，10-邻菲罗啉(phen)和2，2′-联喹啉(bq)。用元素分析、摩尔电导、红外和紫外光谱、磁矩及热分析等方法研究了配合物的组成和性质，表明配合物有两种结构类型，一类是畸变八面体，另一类为平面正方形。 |
| 关键词: 铜 苯甲酰缬氨酸 二胺 混配配合物 合成 |
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| Abstract: Four new mixed ligand complexes of copper (Ⅱ) with N-benzoylvaline (Bvalo) and diamine (ethylenediamine, 2,2′-bipyridine, 1,10-phenanthroline and 2,2′-biquinoline) were synthesized and characterized by elemental analyses, infrared and electronic spectra, molar conductance, magnetic moment and thermal analyses. The compositions of the complexes were confirmed to be ［Cu(Bvalo)2(en)2］·3H2O and ［Cu(Bvalo)2(DA)2］·H2O. Some properties of the complexes were studied. |
| Keywords: N-benzoylvaline diamine mixed ligand complexe synthesis |
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| 沈良,龚钰秋.铜(Ⅱ)与N-苯甲酰缬氨酸和二胺类混配配合物的合成与表征[J].无机化学学报,1997,13(2):197-200. |
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