| 四-(对甘-缬二肽苯基)卟啉及其过渡金属配合物的研究 |
| STUDY ON TETRA (p-GLYCYLVALINEPHENYL) PORPHYRIN AND ITS TRANSITON METAL COMPLEXES |
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| 摘要: 本文以四-(对氨基苯基)卟啉和N-氯乙酰缬氨酸为原料，在DMF中首次合成了一种新型的含二肽基团的四苯基卟啉，四-(对甘-缬二肽苯基)卟啉(H2L)，及其Mn(Ⅲ)、Fe(Ⅲ)、Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)、Zn(Ⅱ)配合物MnLCl, FeLCl, CoL, NiL, CuL, ZnL，用元素分析、红外光谱、电子光谱、荧光光谱、氢核磁共振谱和激光拉曼光谱进行了表征，研究了这些新型配合物与含N、S碱的轴向加合性质。 |
| 关键词: 四-(对甘-缬二肽苯基)卟啉 过渡金属配合物 光谱 轴向配体 |
| 基金项目: |
| Abstract: A new tetra (p-glycylvalinephenyl) prophyrin (H2L) and its transition metal Mn(Ⅲ)、Fe(Ⅲ)、Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ) and Zn(Ⅱ) complexes MnLCl, FeLCl, CoL, NiL, CuL, ZnL have been synthesized by the direct reaction of tetra (p-aminophenyl) porphyrin with N-chroloacetylvaline in DMF. Their structures are characterized by elemental analysis, UV, IR, FR, 1H NMR and Resonance Raman spectra. The axial additive property of the complexes with bases containing nitrogen and sulfur atoms are studied. |
| Keywords: tetra (p-glycylvalinephenyl) porphyrin transition metal complex spectrum axial ligand |
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| 倪春林,王静秋,秦子斌.四-(对甘-缬二肽苯基)卟啉及其过渡金属配合物的研究[J].无机化学学报,1997,13(2):191-196. |
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