| 平面四方型混合配体配合物［Pd(γ-CH3py)2(mnt)2］的合成和晶体结构 |
| SYNTHESIS AND CRYSTAL STRUCTURE OF ［Pd(γ-CH3py)2(mnt)］,AN COORDINATION COMPOUND WITH MIXED LIGANDS IN A SQUARE PLANAR CONFIGURATION |
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| 摘要: 本文报道标题化合物(其中γ-CH3py是对-甲基吡啶，mnt=?的合成、鉴定和单晶结构。化合物晶体属三钭晶系，P1空间群，晶胞内分子数为2。分子中与Pd(Ⅱ)配位的四个原子呈平面四方形。讨论了结构与二阶、三阶非线性光学效应的关系。 |
| 关键词: 合成 晶体结构 钯 平面四方型 非线性光学效应 |
| 基金项目: |
| Abstract: This paper describes the synthesis, characterization and X-ray single crystal structure of the new title compound where γ-CH3py is γ-methylpyridine and mnt represents maleonitriledithiolate. It crystallizes in triclinic system and space group P1. It is confirmed that four coordinating atoms arround Pd(Ⅱ) cation form a square planar configuration. The relation between structure and the second and third order nonlinear optical properties is preliminarily discussed. |
| Keywords: synthesis crystal structure palladium square planar nonlinear optical property |
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| 王寿柏,秦金贵,刘道玉,罗保生,谌了容.平面四方型混合配体配合物［Pd(γ-CH3py)2(mnt)2］的合成和晶体结构[J].无机化学学报,1997,13(2):173-178. |
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