| 八烷氧基2，3-萘酞菁锌(Ⅱ)的合成及荧光光谱研究 | |
| STUDIES ON SYNTHESIS AND FLUORESCENCE SPECTRA OF THE OCTAALKOXY 2，3-NAPHTHALOCYANINES ZINC(Ⅱ) | |
| 摘要: 采用在强有机碱1，8-二氮杂双环［5,4,0］+--7烯(简称DBU)存在下的醇溶剂中，由“分子碎片”与锌盐通过模板反应的新方法合成了一组八烷氧基2，3-萘酞菁锌配合物(Zn(RO)8NPc, 其中R=C4H9、 C8H17、C12H25, NPc=C48H16N8)。产物进行了元素分析和红外光谱分析 | |
| 关键词: 八烷氧基 萘酞菁锌 DBU 荧光光谱 合成 | |
| 基金项目: | |
| Abstract: 5, 9, 14, 18, 23, 27, 32, 36-octaalkoxy 2,3-naphthalocyanines(Zn(RO)8NPc, R=C4H9、 C8H17、 C12H25, NPc=C48H16N8) and ZnNPc have been synthesized by a new method—the template reaction of “molecular fragments”—1,4-dialkoxy-2,3-dicyanonaphthalene or 2,3-dicyanonaphthalene with anhydrous zinc chloride in n-amyl alcohol in the presence of 1,8-diazabicyclo［5,4,0］-undec-7-ene(DBU). These coordination compounds have been characterized by elemental analysis and IR. The fluorescence properties of the coordination compounds at 12℃ (excited at 700 nm, 5.0×10-5 mol·dm-3) have been studied in different organic solvent. | |
| Keywords: octaalkoxy 2,3-naphthalocyanine zinc DBU fluorescence spectrum synthesis | |
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| 杨素芩,刘尔生,陈耐生,黄金陵,卜平,段武彪,吴谊群,左霞,毛桂杰.八烷氧基2，3-萘酞菁锌(Ⅱ)的合成及荧光光谱研究[J].无机化学学报,1997,13(1):83-88. | |
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