八—4—(四氢糠氧基)双酞菁衍生物钕(Ⅲ)、铕(Ⅲ)的合成和LB膜的气敏性
PREPARATION OF Nd(Ⅲ),Eu(Ⅲ) OCTA 4(TETRAPHYDROFURFUROXY) PHTHALOCYANINE AND SENSIBILITY ELECTROCHEMISTRY OF THEIR LB FILMS
作者单位
张引 吉林省教育学院化学系, 长春130022 
辛春梅 吉林省教育学院化学系, 长春130022 
王丹 吉林省教育学院化学系, 长春130022 
梁冰洁 中科院长春应用化学研究所, 长春130022 
陈文启 中科院长春应用化学研究所, 长春130022 
席时权 中科院长春应用化学研究所, 长春130022 
摘要: 
关键词: 希土双酞菁衍生物  LB膜  气敏性  荧光性  紫外可见光谱  合成
基金项目: 
Abstract: In this paper, Nd(Ⅲ),Eu(Ⅲ)-octa-4(tetraphydrofurfuroxy) phthalocyanine was synthesized and characterized by elemental analysis, IR, 1H NMR. The compounds have good film forming ability. The LB films deposited on gold comb electrode by the LB technique according to the z-type. The gas sensibility of LB films was determined. The results show that the films have good sensibility and selectivity for the vapor of NH3. And it comparable with coper (Ⅱ) phthalocyanine.
Keywords: rare earth bisphthalocyanine derivatives  LB-film  gas sensibility  fluorescence  UV-Vis  synthesis
投稿时间:1995-12-18 
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张引,辛春梅,王丹,梁冰洁,陈文启,席时权.八—4—(四氢糠氧基)双酞菁衍生物钕(Ⅲ)、铕(Ⅲ)的合成和LB膜的气敏性[J].无机化学学报,1996,12(4):436-439.
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