| 三(2-苯并咪唑亚甲基)胺硝酸镍(Ⅱ)配合物的合成及结构 | |
| SYNTHESIS AND CRYSTAL STRUCTURE OF NICKEL NITRATE DONATED BY TRIS(2-BENZIMIDAZYLMETHYL) AMINE | |
| 摘要: 三(2-苯并咪唑亚甲基)胺简称NTB与Ni(Ⅱ)的硝酸盐形成配合物C28H35N9O9S2Ni.本文报道其合成,红外光谱及晶体结构。该化合物为三斜晶系,空间群P1,a=9.650(3),b=12.716(2),c=14.436Å,α=11.46(2),β=91.66(3),γ=97.55(2)°,V=1718(2)Å3,Z=2,F(000)=793,Dc=1.48g/cm3,Mr=764.18,μ=0.748mm-1.用CAD4四圆衍射仪,MoKα射线收集数据。结构由重原子法解出。全矩阵最小二乘法修正,最终偏离因子R=0.065,Rw=0.072.结果表明,晶体中每个Ni(Ⅱ)与NTB的四个N原子及水分子的O原子配位,形成扭曲的三角双锥构型。Ni位于结构的中心。 | |
| 关键词: NTB 镍 合成 晶体结构 | |
| 基金项目: 天津市高等教育局重点学科资助项目 | |
| Abstract: The complex C28H55N9O9S2Ni was prepared by tris (2-benzin idazylm ethyl) and ine w ith nickel nitrate The synthesis, IR spectrum properties and the crystal struture are reported now.The crystals are triclinic, space group P1,a=9.650(3),b=12.716(2),c=14.436Å,α=11.46(2),β=91.66(3),γ=97.55(2)°,V=1718(2)Å3,Z=2,F(000)=793,Dc=1.48g/cm3,using the CAD4 diffractometer and MoKα diffraction. The crystal structure is deter-mined by the Patterson and Fourier synthesis, Full-matrix least-square refinements, lead to the reliability factor R=0.065, Rw=0.072.The nickel atom is coordinated with the four nitrogen atom s from the NTB and one oxygen atom from a H2O molecule to form a distorted trigonal-bipyramid, where the nickel(Ⅱ)sets in the centre of the configuration. | |
| Keywords: NTB nickel synthesis crystal structure | |
| 投稿时间：1995-07-11 | |
| 摘要点击次数: 2165 | |
| 全文下载次数: 1978 | |
| 缪方明,周卫红,韩建国,樊志,王瑾玲,王宏根,姚心侃,霍建忠,乔艳红.三(2-苯并咪唑亚甲基)胺硝酸镍(Ⅱ)配合物的合成及结构[J].无机化学学报,1996,12(3):234-239. | |
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