| 双安息香缩乙二胺的合成及其配位性质 |
| SYNTHESISAND COORDITATIVE PROPERTIES OF BIS-BENZOIN-SEMIETHYLENEDIAMINE |
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| 摘要: 合成了双安息香缩乙二胺及其与Ni(Ⅱ)、Pd(Ⅱ)、Pt(Ⅱ)、Zn(Ⅱ)、Cd(Ⅱ)和Hg(Ⅱ)的配合物,并经质谱、红外光谱、元素分析和电子光谱等方法所表征;测定了溶液中配合物的稳定常数,并就该配体的特殊配位性质进行了讨论。 |
| 关键词: 双安息香缩乙二胺 合成 Ni(Ⅱ) Pd(Ⅱ)Pt() Zn(Ⅱ) Cd(Ⅱ) Hg(Ⅱ) |
| 基金项目: |
| Abstract: Bis-benzion-semiethylenediamine was synthesized by condensation of benzoin with ethylenediamine and its complexes of Ni(Ⅱ),Pd(Ⅱ),Pt(Ⅱ),Zn(Ⅱ),Cd(Ⅱ) and Hg(Ⅱ) were synthesized.They were all characterized by elemental analysis,IR,MS and electronic spectra. The stability constantsof these complexesin DMSO-H2O solution were determined and the special coordinating properties of this ligand was studied. The results showed that because the ligand is cavernous the stability of these complexes is related to radiusof metal ion. |
| Keywords: bis-benzoin-semiethylenediamine synthesis Ni(Ⅱ) Pd(Ⅱ) Pt(Ⅱ) Zn(Ⅱ) Cd(Ⅱ) Hg(Ⅱ) |
| 投稿时间：1995-07-24 |
| 摘要点击次数: 1263 |
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| 钟超凡,邓建成,童珏,朱文松,申桃江,谢超.双安息香缩乙二胺的合成及其配位性质[J].无机化学学报,1996,12(2):167-171. |
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