| 含异硫氰酸苯酯裂解碎片的铁硫羰合簇取代衍生物的合成与表征 | |
| SYNTHESESAND CHARACTERIZATION OF IRON CARBONYL CLUSTERS WITH PHENYLISOCYANIDO AND THIO LIGANDS FROM CLEAVING OF THE PHENYLISOTHIOCYANATE | |
| 摘要: | |
| 关键词: 裂解碎片 三核铁簇 合成 | |
| 基金项目: 内蒙古自然科学基金;兰州化物所 OSSO开放室基金资助项目 | |
| Abstract: New mono-and di-substituted derivatives of Fe3(CO)9(μ3-S)2 were synthesized by reaction of C6H5NCS with Fe3(CO)12 atroom temperature.Their structure were characterized by means of IR(νCO),MS,1H NMR,13C NMR,elemental analysis and X-ray four cycle diffractometer.The results showed that the formulas of the cluster compounds are Fe3(CO)8(CNC6H5)(μ3-S)2 and Fe3(CO)7(CNC6H5)2(μ3-S)2 respectively. | |
| Keywords: synthesis cleaving fragment trinuclear iron | |
| 投稿时间：1995-05-15 | |
| 摘要点击次数: 1605 | |
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| 陆庆玮,王一兵,吴宝山,索全伶,刘莲云,支继武,刘树堂,胡襄.含异硫氰酸苯酯裂解碎片的铁硫羰合簇取代衍生物的合成与表征[J].无机化学学报,1996,12(1):111-113. | |
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