| 2, 6─二甲酸─4─取代苯酚双缩苯甲酰肼双核铜(Ⅱ)配合物的合成与磁性 |
| SYNTHESIS AND MAGNETIC PROPERTIES OF BINUCLEAR COPPER COMPLEXES$WITH 2, 6-DIFORMYL-4-SUBSTITUDEDPHENO DI(BENZOYLHYDRAZONE) |
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| 摘要: 本文合成并表征了两个新的双核铜(Ⅱ)配合物:〔Cu2(L)(μ─Cl)Cl2〕,配体L为2,6─二甲酰─4─甲基苯酚双缩苯甲酰肼,取代基分别为氯(L2)和叔丁基(L2).配合物具有相同的组成和配位构型.变温磁化率(4-300K)测定结果表明,由于取代基不同,其磁交换参数分别为-46.2cm-1(L2)和-57.6cm-1(L2). |
| 关键词: 双铜配合物 取代基 磁性 |
| 基金项目: 国家自然科学基金 |
| Abstract: Two binuclcar copper complexes(Cu2(L)(μ-Cl)Cl2)have been synthesized and characterized The ligand L denotes,2,6-diformyl-4-substitudedphenol di(benzoylhydrazone),where the substituent are chloride(L2)and tert-butyl(L2),respectively. The complexes have the same constitution and coordination environment.The determination of variable-temperature magnetic suseeptibilities indicates that the magnetic exchanges parmeters are -46.2cm-1(L1)and -57.6cm-1(L2), respectively. |
| Keywords: binuclear copper complex substituent magnetic property |
| 投稿时间：1994-10-06 |
| 摘要点击次数: 1175 |
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| 程鹏,阎世平,廖代正,姜宗慧,王耕霖.2, 6─二甲酸─4─取代苯酚双缩苯甲酰肼双核铜(Ⅱ)配合物的合成与磁性[J].无机化学学报,1995,11(3):272-275. |
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