| 腙型双冠醚的合成和性质Ⅱ. |
| SYNTHESIS AND PROPERTY OF THE HYDRAZONE TYPE BIS-CROWN ETceRS Ⅱ. |
|
| 摘要: 4'-甲酰基苯并-15-冠-5、4'-乙酰基苯并-15-冠-5分别与肼和芳杂环二肼缩合得到五种新的腙型双冠醚.用电导法研究了它们与碱金属离子的配位性质. |
| 关键词: 腙型双冠醚 合成 碱金属 配位 |
| 基金项目: |
| Abstract: Five new hydrazone type his-crown ethers with benzo-15-crown-5 moieties were synthesised by the reaction of hydrazine or aromatic hoterocylic bishydrarine and 4'-formyl or 4'-acetyl benzo-15-crown-5 ethers with good yield. All these new his-crown ethers were characterized by clemental analysis, IR and 1HNMR. The stoichidmetry or the complexes formed by the his-crown ethers with alkali metal canons was determined by electroconductivity titration of the ligand with alkali metal chloride solution. |
| Keywords: bis-crown ether synthesis alkall metal complex |
| 投稿时间：1994-09-09 |
| 摘要点击次数: 1483 |
| 全文下载次数: 1453 |
| 王志林,陆国元,赵永忠,耿金龙.腙型双冠醚的合成和性质Ⅱ.[J].无机化学学报,1995,11(2):215-218. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
