| 三(8－羟基喹啉)镍(Ⅱ)合高氨酸钠Na[NiQ2(HQ)](ClO4)的制备和晶体结构 |
| CRYSTAL STRUCTURE OF TRI(8-QUINOLINOL)NICKEL PERCHLORATE SODIUM Na[NiQ2(HQ)](ClO4) |
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| 摘要: 在使用8-羟基喹啉为配体试图制备钆和镍的异双核配合物时,分离出Na[NiQ2(HQ)](ClO4)单晶,首次测定了它的晶体结构.Rane等曾从NiQ2·2H2O的晶胞参数推测出NiQ2·2H2O的键参数[1].最近我们将高氯酸钇、醋酸镍和8-羟基喹啉在丙酮中反应,制备了[YQ(HQ)2][NiQ3(ClO4),并测定了它的晶体结构[2]. |
| 关键词: 8－羟基喹啉 镍 红外光谱 晶体结构 |
| 基金项目: |
| Abstract: Na[NiQ2(HQ)](ClO4)was synthesized. The crystal structure of it showed that the crystal is monoclinic, space group P2/n with a=13.546(7)Å, b=12.146(6)Å, c=16.421(7)Å,β=101.02(4)°. There are two anions 8-quinolinol and a neutral one in six-coordinated distorted octahedral geometry of(NiQ2(HQ)). IR spectra for it were recorded. |
| Keywords: 8-quinolinol nickel complex IR spectrum crystal structure |
| 投稿时间：1994-05-30 |
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| 张明杰,黄春辉,徐光宪.三(8－羟基喹啉)镍(Ⅱ)合高氨酸钠Na[NiQ2(HQ)](ClO4)的制备和晶体结构[J].无机化学学报,1995,11(2):212-214. |
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