| 双核铜配合物[Cu2(C6H5COO)4(C9H7N)2]·2H2O |
| SYNTHESIS AND CRYSTAL STRUCTURE OF DICOPPER(Ⅱ)COMPLEX [Cu2(C6H5COO)4(C9H7N)2]·2H2O AND PROPERTIES STUDY |
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| 摘要: 本文首次利用铜粉和过氧化苯甲酰的氧化加成反应,在喹啉存在下合成了新的双核铜配合物[Cu2(C6H5COO)4(C9H7N)2]·2H2O.配合物进行了元素分析、摩尔电导、热重分析、红外光谱、电化学等测试;并经X-射线单晶结构分析;确定了配合物的结构.配合物属正交晶系,空间群Pbca,a=19.879(2)β,b=16.982(5)β,c=11.600(4)β,α=β=γ=90°,V=3916A3,Z=4,D=1.475g·cm-3,R=0.02599,Rw=0.02885. |
| 关键词: 铜 过氧化苯甲酰 氧化加成反应 晶体结构 |
| 基金项目: 省自然科学基金;配位化学重点实验室资助 |
| Abstract: Dibenzoyl peroxide undergoes oxidative addition to metallie cooper with quinoine in a mixed solvent and affords the binuelcar complex[Cu2(C6H5COO)4(C9H7N)2]·2H2O.It was characterized by elemental analysis, electrical conductivity, thermogravimetric,infrared spectra,and electrochemistry. Crystal is orthorhombic system. Space group Pbac.with cell parameters.a=19.879(2), b=16.982(5), c=11.600(4)Å, α=β=γ=90°, Z=4, V=3916Å3, R=0.02598 and Rw=0.02885 |
| Keywords: copper dibenzoyl peroxide oxidative addition reaction crystal structure |
| 投稿时间：1994-07-25 |
| 摘要点击次数: 1805 |
| 全文下载次数: 1916 |
| 王冬梅,薛宝玉,杨瑞娜,侯益民,胡晓院,金斗满,罗保生,谌了容.双核铜配合物[Cu2(C6H5COO)4(C9H7N)2]·2H2O[J].无机化学学报,1995,11(2):180-184. |
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