| 铜(Ⅱ)/铁(Ⅲ)Salen双核配合物的再研究 |
| REINVESTIGATION ON THE Cu(Ⅱ)/Fe(Ⅲ)BINUCLEAR COMPLEX WITH SALEN LIGAND |
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| 摘要: 本文设计了两种不同合成路线,分别制得了相应的铜(Ⅱ)/铁(Ⅲ)Salen双核配合物[Salen代表N,N'-亚乙基双(水杨醛缩亚胺)二价酸根].通过对这两种产物的元素分析、红外光谱、电子光谱、磁化率及质谱的测定,确定它们属于同一种双核配合物,化学组成为CuFe(Salen)Cl3·1/2S(S=CHCl3或CHCl2),并对它们的结构进行了讨论. |
| 关键词: 双核配合物 Salen 铜(Ⅱ)/铁(Ⅲ) |
| 基金项目: |
| Abstract: In this paper two different synthetic methods for the Cu(Ⅱ)/Fe(Ⅲ)Salen complex were described,and the same binuclear complexes CuFe(Salen)Cl3·1/2S were obtained,(where Salen stands for the dianion of N,N'-ethylene-his(salicylidcncdi and S dcnotCs CHCl3 or CH2Cl2),as confirmed by clemental analysis,infrared,electronic and mass spectra,and magnetic susceptibility measurements.Based on the information as mentioned above,a tantative dimerie structure was suggested. |
| Keywords: binuclear complex salen Cu(Ⅱ)/Fe(Ⅲ) |
| 投稿时间：1994-05-10 |
| 摘要点击次数: 1929 |
| 全文下载次数: 1704 |
| 林纪筠,杨维达.铜(Ⅱ)/铁(Ⅲ)Salen双核配合物的再研究[J].无机化学学报,1995,11(2):126-129. |
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