| 石墨－AlCl3的熔盐电解合成及电化学性能 |
| ELECTROLYTIC SYNTHESIS OF GRAPHITE-AlCl3 IN MAlCl4 MELT SALT AND ELECTROCHEMICAL PROPERTIES |
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| 摘要: 自六十年代以来,随着石里扬人化合物(GIC)材料在超导体、催化剂、高能量密度电池和有机反应试剂中的出现，人们对石墨层间化合物制备[1-3]、性质和结构[4-7]进行了详细研究. |
| 关键词: 石墨插入化合物 电解合成 阴极材料 |
| 基金项目: 中国科学院兰州分院科技发展基金 |
| Abstract: The graphite intercalation compound AlCl3-GIC has been prepared by electrolytic method in MAlCl4 melt salt with graphite anode stainless steel cathode. The electrode reaction equation in the electrolytic process can be written as. nC+M+AlCl4-→CnAlCl3+1/2Cl2+M,where the number n of carbon atom is inversely proportional to quantity of electricity passed(n=23.9~14.2). Mean composition and structure of the electrolytic products at various condition were measured by chemical analysis and X-ray powder diffraction. The possibility and the behavior of AlCl3-GIC as positive electrodc of Li cell were investigated by typical voltammetric curve and discharge test in 1.5mol·1-1LiAlCl4-propylene carbonate(PC). |
| Keywords: graphite intercalation compound electrolytic synthesis cathode material |
| 投稿时间：1994-03-31 |
| 摘要点击次数: 1526 |
| 全文下载次数: 1922 |
| 房艳,康永峰,葛芹,余世英.石墨－AlCl3的熔盐电解合成及电化学性能[J].无机化学学报,1995,11(1):97-101. |
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