| 过氧多酸研究──Ⅱ.K12H2[W(OH)5(H2O)(VO(O2)2-OH-VO(O2)2)5]·2H2O的合成及表征 |
| STUDIES ON PEROXOPOLYOXOMETALATES Ⅱ.SYNTHESIS AND CHARACTERIGATION OF K12H2[W(OH)5(H2O)(VO(O2)2-OH-VO(O2)2)5]·2H2O |
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| 摘要: 无机过氧化合物作为活性氧源在有机合成反应中显示了独特的催化氧化性能,特别是过氧多酸的应用倍受重视. |
| 关键词: 白钨酸 过氧化氢 μ-氧·二[二过氧根·氧合钒(V)酸盐 氢键 |
| 基金项目: 国家自然科学基金 |
| Abstract: The mixed metal peroxide,K12H2[W(OH)5(H2O)(VO(O2)2-OH-VO(O2)2)5]·2H2O, was obtained from the reaction of WPTA, KVO3 and H2O2. This compound was characterized by elemental analysis,IR spectra, DTA-TG thermal analysis and UV spectra.Its structure was also suggested. |
| Keywords: white powder tungstic scid(WPTA) hydrogen peroxide μ-oxo-bis (oxodiperoxovanadate) hydrogen hond |
| 投稿时间：1993-12-25 |
| 摘要点击次数: 1336 |
| 全文下载次数: 1487 |
| 张权,岳斌,朱思三,金松林,谢高阳.过氧多酸研究──Ⅱ.K12H2[W(OH)5(H2O)(VO(O2)2-OH-VO(O2)2)5]·2H2O的合成及表征[J].无机化学学报,1994,10(4):439-442. |
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