| 单取代苯丙氨基酸卟啉配合物的催化性质研究 |
| STUDIES ON CATALYTIC PROPERTIES OF MONOSUBSTITUTED PHENYLALANINE TETRAPHENYLPORPHYRIN AND ITS COMPLEXES |
|
| 摘要: 初步研究了标题卟啉(H2P)及其三种配合物MP(Cl)[M=Fe(Ⅲ)、Co(Ⅱ)和Mn(Ⅲ)]存在下,用氧气氧化芳醛的催化吸氧动力学曲线。实验发现除H2P外,三种配合物MP(Cl)对芳醛的氧化均具有催化作用,其最高吸氧速度按MnPClMnPCl>CoP顺序减短,还研究了底物、MP(Cl)在反应体系中的浓度及溶剂等因素对催化氧化反应的影响。 |
| 关键词: 苯丙氨基酸 金属卟啉 催化氧化 |
| 基金项目: |
| Abstract: The oxidation of aromatic aldehydcs with O2 has been investigated in the presence of MP(Cl). The oxygen uptake volume of MP(Cl) during the course of theseaction was measured.It was observed the complexes can all catalyze the oxidation of aromatic aldehydes, while HZP is inactive. The order of O2 maximum uptaking rates are MnPCI |
| Keywords: phenylalanine metalloporphyrin catalytic oxidation |
| 投稿时间：1993-06-19 |
| 摘要点击次数: 1340 |
| 全文下载次数: 1708 |
| 倪春林,王静秋,贾密英,秦子斌.单取代苯丙氨基酸卟啉配合物的催化性质研究[J].无机化学学报,1994,10(3):317-320. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
