| PdCOM+(M=Li,Na,K)体系中M+的助催化性能的成键能研究 |
| A THEORITICAL STUDY OF PdCOM+ COMPLEXES AS A SIMPLE MODEL OF A PROMOTED CATALYST WITH THE BONDING ENERGY CRITERION |
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| 摘要: 本文采用成键能判据[1]探讨了模型化合物PdCOM+分子轨道成键性质和原子间化学键强度,进而说明M+的助催化性能,得到与文献[2]和实验[3]相符的结论。 |
| 关键词: 成键能 助催化剂 |
| 基金项目: 国家自然科学基金 |
| Abstract: With bonding energy criterion and EHMO method,a theoritical study of promoted catalyst M+(M =Li,Na, K) in PdCOM+ complexes has been carried out.The bonding energyEb(i) of MO and Eb(AB) between atoms have been obtained From Eb(i) and Eb(AB),the effectof promoted catalyst M+(M=Li,Na.K) in PdCOM+ complexes has been explained and thecatalytic activity order of Li+,Na+,K+ in PdCOM+ has been predicted. |
| Keywords: bonding energy promoted catalyst |
| 投稿时间：1993-07-21 |
| 摘要点击次数: 1462 |
| 全文下载次数: 1587 |
| 王长生,孙仁安,杨峥,于迎春,杨忠志.PdCOM+(M=Li,Na,K)体系中M+的助催化性能的成键能研究[J].无机化学学报,1994,10(3):284-288. |
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