| 水合希土硝酸盐与本并及单环己基-12-冠-4配合物的合成、性质及晶体结构 |
| SYNTHESES AND PROPERTYS OF RARE EARTH NITRATE COMPLEXES WITH BENZO-12-C-4 AND CYCLOHEXYL-12-C-4 |
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| 摘要: 在乙腈介质中合成了苯并-12-冠-4(简称B-12-C-4)和单环己基-12-冠-4(简称Cy-12-C-4)的六种希土配合物:RE(NO3)3·B-12-C-4(RE=Pr,Gd,Yb,Lu),RE(NO3)3·Cy-12-C-4(RE=La,Lu).研究了它们的IR及1HNMR性质,并测定了四种单晶的结构。用INDO法计算了Lu(NO3)3·B-12-C-4,Lu(NO< |
| 关键词: 合成 结构 性质 水合希土硝酸盐 苯并-12-冠-4 单环已基-12-冠-4 |
| 基金项目: |
| Abstract: By reaction of RE(NO3)3· nH2O with benzo-12-C-4 or cyclohexyl-12-C-4 (in molar ratio 1:1) in acetonitrile, six anhydrous complexes, RE(NO3)3·benzo-12-C-4(RE = Pr, Gd,Yb, Lu) and RE(NO3)3·cyclohexyl-12-C-4(RE= La, Lu), were obtained. They were characterized by IR and 1H NMR. The crystal structures of RE(NO3)3·benzo-12-C-4(RE= Gd,Lu) and RE(NO3)3·cyclohexyl-12-C-4(RE = La, Lu) were determined by X-ray diffraction analysis. The electronic structures of Lu(NO3)3·L(L=benzo-12-C-4, cyclohexyl-12-C-4)were studied by INDO method. The results showed that the stability of rare earth complexes of benzo-12-C-4 decreased within Pr, Gd, Yb, Lu series, and complexes of cyclohexyl-12-C-4 were more stable than complexes of benzo-12-C-4. It was found that the ether rings of the ligands occured some deformation when complexed with different rare earth ions. |
| Keywords: syntheses structure property hydrated rare earth nitrate benzo-12-C-4 cyclohexyl-12-C-4 |
| 投稿时间：1993-04-21 |
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| 王瑞瑶,李振祥,金钟声,倪嘉缵.水合希土硝酸盐与本并及单环己基-12-冠-4配合物的合成、性质及晶体结构[J].无机化学学报,1994,10(2):172-177. |
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