| 三价铬与丙二酸形成的配合物的热解过程研究 |
| STUDY ON THE THERMAL DECOMPOSITION OF THE CHROMIUM(Ⅲ) MALONATE COMPLEX |
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| 摘要: 利用热重分析及原位红外光谱等方法,定性、定量地研究了三价铬和丙二酸形成的配合物[Cr(C3H2O4)(H2O)4][Cr(C3H2O4)2(H2O)2]·4H2O的热解过程,提出了室温至400℃下的详细热解途径。基于多种实验结果,分析了螯合物中六 |
| 关键词: 铬与羧酸所形成的配合物 热解 |
| 基金项目: |
| Abstract: he thermal decomposition of chromium(Ⅲ) malonate complex [Cr(C3H2O4)(H2O)4][Cr(C3H2O4)2(H2O)2]·4H2O has been studied quantitatively and qualitatively by thermogravimetric analysis and in situ variable-temperature IR spectroscopy, the detail process from R. T. to 400℃ is proposed. According to a great deal of experiments, the fragmentation type of the coordinating bidentate malonate was analyzed,and verified by FAB-MS data as well. |
| Keywords: chromium complex carboxylate complex thermal decomposition |
| 投稿时间：1993-03-13 |
| 摘要点击次数: 1278 |
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| 谢伟文,郑瑜,张琳娜,蔡素华,傅桂香,朱自莹.三价铬与丙二酸形成的配合物的热解过程研究[J].无机化学学报,1994,10(2):146-150. |
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