| 5-(4-氯苯基)-10,15,20-三苯基卟啉及其配合物的合成、结构表征及热分解机理 |
| SYNTHESIS, STRUCTURAL CHARACTERIZATION AND THERMAL DECOMPOSITION MECHANISM OF 5-(4-CHLORO-PHENYL)-10,15,20-TRIPHENYLPORPHYRIN AND ITS COORDWATION COMPOUNDS |
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| 摘要: 合成了标题卟啉配体及其钴、镍、铜、锌和铁的五种配合物。对它们进行了元素分析、UV、IR和荧光光谱等结构表征。用DTA、TG、DSC等手段研究了这些新化合物的热稳定性及热分解机理,实验结果与HMO方法计算的结果一致。 |
| 关键词: 金属卟啉配合物 热分解机理 |
| 基金项目: 国家自然科学基金 |
| Abstract: Five new complexes of the title porphyrin have been synthesized, their structures were characterized by elemental analysis, UV, IR, fluorcsccncc spectrum and so on, Their thermal stability and thermal decomposition mechanism were studied by DTA,TG, DSC and GC method. The experiment result are in accord with the calculational result from HMO method. |
| Keywords: metalporphyrin complex thermal decomposition mechanism |
| 投稿时间：1993-03-04 |
| 摘要点击次数: 1693 |
| 全文下载次数: 1999 |
| 王静秋,贾密英,杨爱群,黄应军,舒红兵,秦子斌.5-(4-氯苯基)-10,15,20-三苯基卟啉及其配合物的合成、结构表征及热分解机理[J].无机化学学报,1994,10(2):141-145. |
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