两种新型植物激素燃烧热的测定及生成焓的计算 |
CALCULATION ON ENTHALPIES OF STANDARD FORMATION OF TWO NEW PLANT HORMONES |
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摘要: 本文报道了用精密转动弹量热计测定两种新型植物激素2-[2-氯苯胺基)羰基]苯甲酸与Ni(Ⅱ)、Cu(Ⅱ)的配合物的燃烧热,换算得Ni(Ⅱ)、Cu(Ⅱ)配合物的-ΔH分m别为11881.1±6.9,13206.7±7.5KJ·mol-1,计算得它们的分别为2050.5±6.9.639.7±7.5kJ·mol-1. |
关键词: 配合物 燃烧热 生成焓 植物激素 |
基金项目: 国家自然科学基金 |
Abstract: Using a precision rotating-bomb combustion calorimeter, the heats of combustion of twonew plant hormones, the complexes of 2-[(2-chlorophenyl)amino carbonyl] benzoic acid withNi(Ⅱ) and Cu(Ⅱ), were determined tO be-11881. 1±6.9 and -13224.1 ±7.5kJ· mol-1 respectively, the precision of the results being given in s. d. m.. The enthalpies of formation of thesecomplexes have been calculated to be-2094.7±6.9 and -964.6 ±7.5kJ· mol-1 respectively. |
Keywords: complex heat of combustion enthalpy of formation plant hormone |
投稿时间:1992-12-22 |
摘要点击次数: 1803 |
全文下载次数: 1717 |
石进超,杨旭武,李承恩.两种新型植物激素燃烧热的测定及生成焓的计算[J].无机化学学报,1994,10(1):94-96. |
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