| 三核苯甲酸铁配合物[Fe3O(OBZ)6(H2O)3](NO3)(acetone)5(OBZ-=苯甲酸根)的结构和磁性 |
| STRUCTURE AND MAGNETIC PROPERTY OF TRINUCLEAR COMPLEX OF[Fe3O(OBZ)6(H2O)3] (NO3) (ACETONE)5(OBZ-=BENZOATE) |
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| 摘要: 合成了三核苯甲酸铁配合物[Fe3O(OBZ)6(H2O)3](NO3)(acetone)5.测定了其晶体结构。其中三个铁形成等边三角形结构。配合物的变温磁化率表明,分子内三个铁之间有弱的反铁磁性交换作用,J=-33.18cm-1.分子之间则有更弱的反铁磁性交换作用,zJ'=-1.14cm-1. |
| 关键词: 三核铁配合物 苯甲酸 磁性 |
| 基金项目: |
| Abstract: The trinucleariron complex of [Fe3O(OBZ)6(H2O)3] (NO3)(acetone)5 (OBZ-=benzoate)hasbeen synthcsizcd. Its crystal structure has been determined and shows that three iron atoms inthe complex form an equilateral triangle. The variable temperature magnetic susceptibility forthe complex shows that there is an antiferromagnetlc exchange interaction with J=-33.18cm-1 among three iron atoms, and a nore weakly antiferromagnetic exchange interaction with zJ'=-1.14cm-1 intermolecules. |
| Keywords: trinucleariron complex benzoic acid magnetism |
| 投稿时间：1993-01-10 |
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| 付德刚,王国雄,唐雯霞,郁开北.三核苯甲酸铁配合物[Fe3O(OBZ)6(H2O)3](NO3)(acetone)5(OBZ-=苯甲酸根)的结构和磁性[J].无机化学学报,1994,10(1):63-68. |
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