RbEuI3和CsEuI3的合成及结构与性质研究
SYNTHESIS, CRYSTAL STRUCTURE AND PROPERTIES OF RbEuI3 AND CsEuI3
作者单位
曹保鹏 山东师范大学化学系, 济南 250014 
赵新华 北京师范大学化学系, 北京 100875 
王世华 北京师范大学化学系, 北京 100875 
摘要: 本文用一步法合成了新化合物RbEuI3与CsEuI3,测定了化合物的组成、结构、熔点、密度、荧光光谱、极谱电位及磁矩,确定了化合物中Eu的价态为正二价.
关键词: RbEuI3  CsEuI3  低价铕化合物
基金项目: 国家自然科学基金资助项目
Abstract: The synthesis of AEuI3(A=Rb,Cs) by a one-step method has been reported.The europium valence,which was determined from the magnetic moment and by polarography,is 2+.The structure of these compounds were determined by X-ray powder diffraction.The composition,lattice parameters,melting point,density,magnetic moment,polarographic potential and fluorescence spectra of AEuI3 have been presented.
Keywords: CsEuI3  RbEuI3  di-vaience rare earth compound
投稿时间:1992-08-07 
摘要点击次数:  1362
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曹保鹏,赵新华,王世华.RbEuI3和CsEuI3的合成及结构与性质研究[J].无机化学学报,1993,9(4):384-388.
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