| 过渡金属氢化物和聚集双键化合物反应的研究——Ⅴ.Cp2MH2(M=Zr,Hf)与RNCS(R=n-Bu,c-C6H11,C6H5,2-C10H7)、CS2的反应 |
| STUDIES ON REACTIONS OF TRANSITION-METAL HYDRIDES WITH HETEROCUMULENES V.REACTIONS OF Cp2MH2 (M=Zr, Hf) WITH RNCS (R=n-Bu, c-C6H11, C6H5, 2-C10H7), CS2 |
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| 摘要: 本文研究了Cp2ZrH2与CS2、RNCS(R=n-Bu,c-C6H11,C6H5,2-C10H7)和Cp2HfH2与c-C6H11NCS的反应,探讨了在这类新型脱硫反应中锆氢与铪氢配合物化学反应性能上的差异.从以上反应中分 |
| 关键词: 前区过渡金属氢化物 二硫化碳 异硫氰酸脂 脱硫反应 |
| 基金项目: 中国科学院科学基金资助的课题 |
| Abstract: A new type of desulfurization reaction was investigated in our laboratory.Two sulfur-bridging homobinuclear complexes (Cp2MS)2 (1,M=Zr; 2,M=Hf) and a novel organohafnium complex Cp2Hf[SC(H)NR]2 (3,R=c-C6H11) were respectively obtained from the reactions of Cp2ZrH2 with CS2,RNCS (R=n-Bu,c-C6H11,C6H5,2-C10H7) and Cp2HfH2 with c-C6H11NCS.The structures of the products were identified by elemental analyses,IR,1H and 13C NMR and MS spectra.The crystal structure of 1 was confirmed by X-ray diffraction.The organic products X=CH2 and CH3X(H) (X=S,NR) were identified by GC-MS analyses in the solution. |
| Keywords: early-transition-metal hydride earbon disulfied isothlocyanate desulfurization |
| 投稿时间：1992-04-04 |
| 摘要点击次数: 2105 |
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| 王梅,陆世维,贝浼智,郭和夫.过渡金属氢化物和聚集双键化合物反应的研究——Ⅴ.Cp2MH2(M=Zr,Hf)与RNCS(R=n-Bu,c-C6H11,C6H5,2-C10H7)、CS2的反应[J].无机化学学报,1993,9(3):275-278. |
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