| 混合配体、希土三元配合物的研究——Ⅷ.羟基乙酸、邻菲罗啉、铕三元固态配合物的合成、性质和量化研究 |
| STUDY ON TERNARY COMPLEXES OF RARE EARTH ELEMENTS Ⅷ. STUDIES ON THE SYNTHESIS, PROPERTIES AND QUANTUM CHEMICAL CALCULATION OF THE TERNARY SOLID COMPLEX OF Eu(Ⅲ) WITH GLYCOLLIC ACID AND PHEN |
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| 摘要: 本文首次报道了羟基乙酸、邻菲罗啉与铕(Ⅲ)的三元固态配合物通过红外、紫外、荧光、热分析、元素与化学分析确定了配合物的化学组成和分子结构;讨论了配合物的摩尔电导和溶解性;采用量子化学INDO/F方法计算了三元固态配合物的电子结构,依据计算结果讨论了三元固态配合物的成键特征。 |
| 关键词: 羟基乙酸 邻菲罗啉 希土配合物 |
| 基金项目: 国家自然科学基金资助项目 |
| Abstract: In this paper we first report the synthesis of the ternary solid complex of Europium with glycollic acid and phen.Its IR,UV,fluorescence,TGA were studied.Its formula was determined to be [Eu(Ⅲ)(CH2COO)3(phen)]·H2O.According to experimental data and referencesOH molecular configuration of the complex is simulated.The electronic structure of the complex is calculated using the INDO/F program which is applicable to calculate the electronic structure of compounds containing lanthanidc elements.Basing on the calculation results of the bonding characters of the ternary solid complex arc discussed. |
| Keywords: glycollic acid o-Phenanthroline rare earth complex |
| 投稿时间：1991-10-09 |
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| 王流芳,任艳平,李一志,彭周人,吴集贵.混合配体、希土三元配合物的研究——Ⅷ.羟基乙酸、邻菲罗啉、铕三元固态配合物的合成、性质和量化研究[J].无机化学学报,1993,9(2):123-127. |
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