希土硝酸盐与胞嘧啶固体配合物的合成和性质研究 |
STUDIES ON THE SYNTHESIS AND PROPERTIES OF RARE EARTH COMPLEXES OF CYTOSINE |
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摘要: 同过渡金属相比,对希土生物化学行为的研究不很充分。胞嘧啶是生命遗传的物质基础,与金属的作用有重要意义。已有人合成了过渡金属与胞嘧啶的配合物,并研究其配位方式[1]。本文研究希土胞嘧啶配合物的合成及性质,这项工作尚未见文献报道。 |
关键词: 胞嘧啶 希土 配合物 |
基金项目: |
Abstract: Eight new complexes of cytosine with Lanthanide nitrate were first synthesized in anhydrous solvent. All the complexes obtained have the general formulae RE(Cyt)2(NO3)3(RE = La, Ce, Pr, Nd, Sm, Eu, Gd, Ho, Cyt = cytosine). Their physico-chemical properties and structure have been elucidated on the basis of elemental analysis, IR and Raman spectra, NMR and thermal analysis. |
Keywords: cytosine rare earth complex |
投稿时间:1991-03-25 |
摘要点击次数: 2187 |
全文下载次数: 1373 |
谢文磊,彭周人,王流芳.希土硝酸盐与胞嘧啶固体配合物的合成和性质研究[J].无机化学学报,1992,8(4):447-450. |
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