咪唑桥联Cu-Co交替异多核和长链配合物的合成、表征和ESR研究 |
SYNTHESIS, CHARACTERIZATION AND ESR STUDY OF IMIDAZOLATE BRIDGED Cu-Co ALTERNATE HETEROPOLYNUCLEAR AND LONG CHAIN COMPLEXES |
|
摘要: 三种咪唑桥Cu-Co交替异三核、二种Cu-Co交替长链配合物已经合成,反射光谱研究确证配合物中咪唑桥的存在。ESR研究阐明了配合物中Cu2+与配体间的成键性质。 |
关键词: 铜 钴配合物 咪唑桥 ESR谱 |
基金项目: |
Abstract: Three imidazolate bridged Cu-Co alternate hcterotrinuclear complexes and two imidazolate bridged Cu-Co alternate long chain complexes were synthesized. By the study of reflectance spectroscopy, it is proved that there exist imidazolate bridges in the all complexes. From the ESR spectra of the complexes, the bond parameters of Cu2+ were calculated and nature of the bond discussed. |
Keywords: copper cobalt complex imidazolate bridge ESR spectra |
投稿时间:1991-04-03 |
摘要点击次数: 1572 |
全文下载次数: 1284 |
陈东,徐兵,唐雯霞.咪唑桥联Cu-Co交替异多核和长链配合物的合成、表征和ESR研究[J].无机化学学报,1992,8(4):353-357. |
查看全文 查看/发表评论 下载PDF阅读器 |
Support information: |
|
|
|