| 混合型杂多化合物Mx[GaW9M3O40]·nH2O的合成和性质 |
| SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLY COMPLEXES Mx[GaW9M’3O40]?nH2O |
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| 摘要: 本文报道了Mx[GaW9M3′O40]nH2O(M′=Mo,V,Ti,Fe(Ⅲ),Co(Ⅱ),Ni(Ⅱ),Mn(Ⅱ);M=k,Na,Gua,Me4N,Et4N,Bu4N)的合成。通过元素分析,阴离子电荷的确定,极谱、IR及UV光谱、可见光谱、ESR、磁化率测定对其进行了表征。并研究了它们在水溶液中对酸碱的稳定性 |
| 关键词: 镓钨杂多化合物 混合型杂多化合物 性质 过渡元素 |
| 基金项目: 国家自然科学基金 |
| Abstract: Trisubstituted heteropoly complexes Mx[GaW9M3′O40]·nH2O have been prepared and characterized by elemental analyses, charge determination on anions, polarograph, IR and UV and Vis spectra, ESR and magnetic susceptibility. Their thermal stability and stability in solution have been also examined. |
| Keywords: trisubstituted heteropoiy complex tungstogallate characterization transition element |
| 投稿时间：1991-01-03 |
| 摘要点击次数: 1164 |
| 全文下载次数: 1480 |
| 刘景福,王敬平,瞿伦玉,陈亚光.混合型杂多化合物Mx[GaW9M3O40]·nH2O的合成和性质[J].无机化学学报,1992,8(3):311-314. |
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