香草醛异烟酰腙与钴、镍、铜、锌和镉配合物的合成和性质研究 |
SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF VANILLIN ISONICOTINOYL HYDRAZONE WITH Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ) AND Cd(Ⅱ) |
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摘要: 本文合成了香草醛异烟酰腙(H2LⅠ)和邻香草醛异烟酰腙(H2LⅡ)与钴(Ⅱ)、镍(Ⅱ)、铜(Ⅱ)、锌(Ⅱ)和镉(Ⅱ)的九个新配合物:M(HLⅠ)2·nH2O[M(Ⅱ)=Co、Ni、Cu、Zn和Cd,n=0,2]和M(HLⅡ)2·nH2O[M(Ⅱ)=Co、Ni、Cu和Zn,n=0-3]。采用 |
关键词: 香草醛 邻香草醛 异烟肼 希夫碱配合物 |
基金项目: |
Abstract: Complexes of cobalt(Ⅱ), nickel(Ⅱ), coppcr(Ⅱ), zinc(Ⅱ) and cadmium(Ⅱ) with vanillin isonicotinoyl hydrazone and o-vanillin isonicotinoyl hydrazonc have been prepared and characterized by elemental analyses, IR spectra, molar conductance, magnetic measurements, electronic absorption spectra, powder X-ray diffraction and differential thermal analyses. The bonding and stereochemistry of the complexes arc discussed. |
Keywords: vanillin o-vanillin isonicotinic hydrazide Schiff base complex |
投稿时间:1990-10-28 |
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王明雄,邓汉芹,娄兆文.香草醛异烟酰腙与钴、镍、铜、锌和镉配合物的合成和性质研究[J].无机化学学报,1992,8(3):255-258. |
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